Glossary.
Materials used in 19th and 20th century Plaster Architecture.
By: JoAnn Cassar and Roberta de
Angelis
P. (plaster - punic wax)
Plaster - 1. Shortened name
for plaster of Paris which is composed of calcium sulphate hemihydrate.
It is also called calcined gypsum. 2. A powder, that forms a pasty mixture
with water and dries to a hard impenetrable solid. Plaster is made using
several formulations. Most plasters contain calcined gypsum or lime as
a binder; some contain clay. Many use sand, hair, jute or straw as extenders.
Some may contain small amounts of salts (potassium sulphate) as accelerants.
Organic materials (blood, glue, casein) and weak acids (citric acid, boric
acid) can act as retardants. Plaster is used as a finish material in wall
and ceiling construction. In its plastic form it can be used for moulding
and casting. Some examples are:
- lime plaster - contains calcium
oxide; used for frescos and wall decoration - gypsum plaster - contains
calcined and ground gypsum; See gypsum cement. - plaster of Paris
- calcined gypsum; used for moulds, sculpture, casts - stucco - contains
gypsum and sand or chalk; used for walls, ceilings, decoration
Museum of Fine Arts, Boston (2000);
Trench (2000)
Plaster of Paris CaSO41/2H2O
- A fine white powder composed of calcium sulphate hemihydrate. Plaster
of Paris obtained its named because it was primarily prepared from gypsum
quarried in the Montmartre district of Paris. It is produced by heating
gypsum, alabaster or selenite, which are composed of calcium sulphate dihydrate,
to temperatures below 250°C (150° - 160°C) to drive off some
of the water of crystallisation. The resulting calcium sulphate hemihydrate
is stable in air, but readily combines with water to form a paste that
rapidly sets (in approximately 30 minutes) to an impenetrable solid. It
generates heat with setting and may expand slightly. When he set is complete
the plaster returns to its original size. Setting can be accelerated by
the addition a small amounts of salts (aluminium sulphate, potassium sulphate)
or retarded by the addition of organic materials (blood, glue, casein).
Plaster of Paris has long been used for moulds, sculpture and casts, and
for the decoration of walls and ceilings. Because plaster of Paris is pure
white and highly porous, the surface is readily soiled and was therefore
often coated. Materials such as tea, gum arabic, waxes, shellac, lime wash
and oil-based paints have been used as coatings. Plaster of Paris is also
frequently painted and oil-gilded. A sealant, such as animal glue, gum
arabic or shellac, is applied first to reduce the porosity of the plaster.
Distemper and oil-based paints are commonly used. It is a component of
alum-gypsum.
Synonyms: calcined gypsum; burnt
gypsum; partially dehydrated gypsum; plaster; calcium sulphate hemihydrate
Wittenburg (1999); Museum of Fine
Arts, Boston (2000); Trench (2000)
Plaster stone
- See gypsum
Museum of Fine Arts, Boston (2000)
Plasterboard - See gypsum
board
Synonyms: wall board; drywall
Museum of Fine Arts, Boston (2000)
Plasterwork - Architectural
finishing or decoration executed in plaster. Plasterwork is used both internally
and externally. The term stucco can also be used to describe all forms
of decorative plasterwork. Renders in clay and gypsum plasters were used
in ancient Egypt, India and China to produce a smooth surface over rough
stone or mud brick walls. The finished surface was often painted or decorated.
The Romans used mixtures of lime and sand to build up preparatory layers
over which finer applications of gypsum, lime, sand and marble dust were
made; pozzolanic materials were sometimes added to produce a more rapid
set. Modelled stucco was employed throughout the Roman empire and plaster
decoration continued to be used in Europe in the Middle Ages. From this
time, surface decoration on building exteriors was produced by incising
patterns into wet plaster or by moulding and free-hand modelling.
Following the fall of the Roman empire, the addition of marble dust to
plaster to allow the production of fine detail and a hard, smooth finish
in hand-modelled and moulded decoration was not used until the Renaissance.
Stucco was widely employed by Mannerist and Baroque artists throughout
Europe because it allowed the production of elaborate high relief but lightweight
figurative decoration. In the 17th and 18th centuries, lime and sand mixes
usually prevailed, with gypsum added to accelerate the set; if the set
was too rapid to allow detailed working of the surface, glue and water
were used to retard it. Various materials were used to increase pliancy,
including curd, glue and almond oil. Marble dust was used where it was
available. Plaster of Paris was used from the 18th century to cast repeat
decoration for walls and ceilings. A further advance in the prefabrication
of ornament was the invention of fibrous plasterwork in the mid-19th century,
in which large sections of lightweight ornament could be quickly produced
and fixed in place. Exterior stucco can be painted using the fresco technique,
in which the pigments become incorporated into the plaster during the setting
process, or with oil-based paints. Other surface finishes include unpainted,
smooth, polished surfaces, sgraffito, scagliola, or decorations made by
pressing objects such as shells, pieces of glass and mirrors, and pebbles
into the plaster while wet, a technique referred to as grotto-work.
Trench (2000)
Plasterer's putty - A hydrated
lime with just enough water added to make a thick paste for use as a hole
or crack filler.
RS Means Building Glossary (undated)
Plasticiser - An additive
that increases the plasticity of another material, such as a a cement paste,
mortar, or concrete mixture, or the flexibility or softness of organic
compounds. plasticisers are usually non-volatile organic liquids or low-melting
solids. Examples are dibutyl phthalate, tricresyl phosphate, ethylene glycol,
and castor oil. Phthalate plasticisers were commonly used in the middle
of the 20th century for PVAC paints. However, since these oily plasticisers
tended to creep and separate with time producing an oily surface and leaving
a brittle substrate, later formulations began using copolymerisation techniques
for film modification rather than plasticisers.
Museum of Fine Arts, Boston (2000);
RS Means Building Glossary (undated)
Polyester resin - A thermoplastic
alkyd type resin. Polyester is made by the reaction of an ester of dihydric
alcohol and terephthalic acid. There are two major types of polyester.
One type, polyethylene terephthalate (PET) was first developed by English
chemists, J. R. Whinfield and J.T. Dickson, in 1941. PET is used to make
Mylar® and other strong moisture-resistant films. The second type,
polybutylene terephthalate (PBT), is mainly used as a moulding compound.
When catalysed, polyesters can harden at room temperature and pressure
with very little shrinkage to produce a clear, colourless fibre, block
or film.
Synonyms: Dacron® [DuPont];
Mylar® [DuPont]; Bio-Plastic; Caroplastic; Castolite; Vestopal; Terylene
[ICI]; Tergal; Tetlon; Palatal; Leguval [Bayer]; Kodel® [Eastman Chemical];
Paraplex [Resinous Products and Chemicals]
Museum of Fine Arts, Boston (2000)
Polyvinyl acetate
[-CH2CH(OOCCH3)-]n - A colourless,
non-toxic thermoplastic resin prepared by the polymerisation of vinyl acetate.
Polyvinyl acetate (PVAC) was first produced in 1912 and was used as an
artists medium in 1938. It is one of the most widely used water-dispersed
resins. Polyvinyl acetate water-based emulsions have been used as latex
house paints, artists' media and common household white glues. Setting
is accomplished by the removal of water due to evaporation or absorption
into a substrate. PVAC resins produce clear, hard films that have good
weather resistance and withstand water, grease, oil and petroleum fuels.
Additional properties are high initial tack, almost invisible bond line,
softening at 30-45*C, good biodegradation resistance, poor resistance to
creep under load and low cost. Polyvinyl acetate resins and copolymers
are also used as hot-melt adhesives, sealants and plastic wood.
Synonyms: PVAc; PVAC; PVA (incorrect);
poly(vinyl acetate); vinyl emulsion; Vinamul [Vinyl Products]; AYAT[Union
Carbide]; Elmers® Glue-All [Borden]; Duratite White Glue [DAP]; Gelva®
[Solutia]; Rivit Glue; Resin W; Polymer Tempera [Borden]; Vinavyl
Museum of Fine Arts, Boston (2000)
Poppy-seed oil - A natural,
colourless, transparent drying oil obtained from the ripe seeds of the
opium poppy (Papaver somniferum) native to the western Mediterranean region.
Poppy seed oil contains linoleic acid (62-72%), oleic acid (10-30%), palmitic
acid (9-10%), stearic acid (1.5-2.5%) and linolenic acid (0-5%) (Serpico
and White 2000). Manufactured poppy seed oil comes primarily from India,
Russia, France and Asia Minor. Cold pressed poppy oil is nearly colourless,
but the hot pressed oil is reddish. Poppy oil dries slower than linseed
oil, but it yellows less, so it was sometimes used with white pigments
starting about the 17th century. The application of oil, including
poppy-seed oil, to the surface of stucco marble has always been quite common
in order to increase the gloss of an already well polished surface.
Synonyms: poppy oil; poppyseed oil;
poppy-seed oil
Wittenburg (1999); Museum of Fine
Arts, Boston (2000)
Portland cement - A
form of cement originally named since it was said to be like Portland Stone
in appearance. See also : cement
English Heritage (2000)
Potassium carbonate K2CO3
- White deliquescent powder. Potassium carbonate is used in the manufacture
of glass, pottery and smalt.
Synonyms: salts of tartar, pearl
ash; potash; salt of wormwood; carbonate of potassium
Museum of Fine Arts, Boston (2000)
Pozzolana - A rosy red
volcanic clay that has been used as a pigment and a component in cement.
Pozzolana is mined in Italy at Pozzuoli near Naples. It is has been used
since ancient times by the Romans. Pozzolana is mixed with lime to form
pozzolana cement. It dries slowly but forms a strong surface. Similar cements
contain trass and Santorin earth. Pozzolana was also a popular pigment
for fresco paintings because it dried quickly to a hard impenetrable surface
like cement. Synthetic pozzolanas are made from slag, burnt clay, HTI powder
(a ceramic material ́high temperature insulationî), PFA (pulverised fuel
ash) and powdered bricks.
Synonyms: terra di pozzuoli; Pozzuoli
red; pozzuolana; gaize cement; puzzolan cement; Santorin cement; silikat-cement;
tarras cement; trass cement
Ashurst (1983)
Museum of Fine Arts, Boston (2000)
Pozzolana cement - 1.
A natural cement, used in ancient times, made by grinding pozzolana with
lime. 2. A cement that contains Portland cement (calcium silicate) mixed
with ground pozzolana (volcanic rock) and sometimes lime.
Pozzolana cement is a hydraulic
cement that hardens with water. It is more resistant to corrosive environments
than plain Portland cement. Pozzolana cement is used for wall coatings.
Artificial pozzolana cement is made with furnace slag (slag cement).
Synonyms: pozzuolana cement; gaize
cement; puzzolan cement; pozzolanic cement; Santorin cement; silikat-cement;
tarras cement; trass cement; slag Cement
Museum of Fine Arts, Boston (2000);
RS Means Building Glossary (undated)
Prussian blue Fe4[Fe(CN)6]3
- A vivid, lightfast blue pigment. Prussian blue, synthetically produced
ferric ferrocyanide, was developed in Berlin in 1704 by Diesbach. It is
made by adding ferric chloride to a boiling solution of hexacyano ferrate.
This forms a white intermediate, called Berlin white, that is oxidised
in air to produce Prussian blue. Prussian blue has deep blue, finely divided
particles that are transparent in watercolours. It has high tinting strength
and is stable to light, although it will fade in strong light and turns
brown in the presence of alkalis or heat. It is therefore inappropriate
to use it on plaster walls. Prussian blue was the first cheap and
stable pigment to replace the costly minerals azurite and lapis lazuli.
It has tremendous tinting strength and is used as a pigment in watercolour
and oil paints. It is listed among the pigments used for colouring stucco
marble in the nineteenth and twentieth century.
Synonyms: ferric ferrocyanide; iron
blue; Turnbull's blue; Paris blue; Milori blue; Chinese blue; bronze blue;
Berlin blue; American blue; Antwerp blue; steel blue; mineral blue; Hamburg
blue; Pigment Blue 27; CI 77510; toning blue; gas blue; new blue; Erlanger
blue; celestial blue; lacquer blue; soluble blue; oriental blue; Persian
blue; potash blue; paste blue; Preussisch Blau (Ger.); bleu de Prusse
(Fr,); Berlinerblau (Ger.); azzurro di Prussia (It.); azul de Prusia (Sp.);
konjo (Jap.); yang lan (Ch.)
Wittenburg (1999); Trench (2000);
Museum of Fine Arts, Boston (2000)
Pumice - A pale grey, porous,
volcanic stone. Pumice is composed of potassium aluminium silicate with
small amounts of iron and alkalis. Its spongy texture is due to numerous
cavities formed by gas bubbles that were trapped when the stone solidified.
Pumice is used as an abrasive. It has also been used as a coarsening agent
for texturising painted surfaces. It is mentioned as grinding stone for
polishing stucco marble by repeated grinding and polishing, performed with
the use of a lot of water and various grinding stones, including pumice
and sandstone for the first and second grinding; serpentine, limestone,
hornblende, jasper, bloodstone for dark surfaces and meerschaum for white
surfaces. Today also synthetic pumice and sanding paper are used for some
of the grinding and polishing steps. Pumice can also be added to lime to
obtain a hydraulic set.
Synonyms: volcanic glass
Wittenburg (1999); Trench (2000);
Museum of Fine Arts, Boston (2000)
Pumicestone paper - An abrasive
paper.
Museum of Fine Arts, Boston (2000)
Punic wax - A processed beeswax
that was used in encaustic paintings. Punic wax was probably made by combining
beeswax with soda lime to produce a waxy soap. Repeated washings in hot
water removed any excess caustic. Experiments conducted in Berlin to recreate
an ancient recipe, yielded flakes of a hard brittle wax that melted between
73-75*C (163-167°F) (Wehlte 1975).
Synonyms: Carthagian wax; eleodoric
wax
Museum of Fine Arts, Boston (2000)
Bibliography
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